A.I.Burshtein, A.A.Zharikov, N.V.Shokhirev
Static and Contact Electron-Transfer Within Photoinduced Geminate Ion-Pairs
Journal of Chemical Physics. 96:(3) 1951-1956, 1992.
Abstract:
The quantum yield and a time of ion pair separation were calculated at
any viscosity of solution and arbitrary distance between them at initial
moment when geminate charge recombination starts. The results are
compared with those obtained in a contact approximation and in a frame
of "exponential model." The way is proposed how to use experimental data
on back electron transfer to answer the questions where the ions were
born and how long an exchange interaction is between them.