ISSN 0038-5387 Soviet Electrochemistry |
|
Electron photoinjection into dilute electrolyte-solutions A. I. Kalugin1, V. V. Konovalov1, E. B. Krissinel'2, A. M. Raitsimring1, N. V. Shokhirev1 1Institute of Chemical Kinetics
and Combustion, Siberian Branch of the USSR Academy of Sciences,
Institutskaya 3, Novosibirsk 630090, USSR Received for publication August 28, 1989; Accepted May XX,
1990 |
|
|
| Abstract |
|
|
| Numerical methods were used to perform an exact calculation of
photodiffusion currents in dilute electrolyte solutions. The exponential
approximation of the y'(x) - potential was shown
to be of limited use. The results of the calculations were compared with
experiments performed at wavelengths, l, of 428
to 193 nm. The values found for the mean distances of
eaq- from the photoelectrode are in good agreement
with data obtained previously for concentrated electrolyte solutions.
Light intensity was found to influence the value of the photoinduced
charge. |