Part 2

Projects  | ABC Tutorials  | IT Tutorials  |   Home

Energy Surfaces

The "atomic" orbital energy levels are the planes in the  -space:

The above intersecting planes form the three energy surfaces, so that  

E 10

E 20

E 30

 

Animation:

The spin-orbit interaction splits the above piecewise-plane energy surfaces into the three separate surfaces:

E 1

E 2

E 3

Note that the E1 and E2 surfaces still touch each other at the point (0, 0) - the pure octahedral case.

g-Tensor Surfaces

All other quantities also form surfaces above the energy plane. In particular, there are three g-value surfaces (gx, gy, gz) for each energy level. For level 3 the g-surfaces are

gz gy gx

 The upper cube facets are at g = 4 and the lower ones at g = -4. The three surfaces are actually the same surface rotated by 120°. The gz-surface is symmetrical with respect to the plane V = 0. The gy and gx surfaces are symmetrical with respect to the appropriate planes as well. 

For better understanding of the three dimensional surfaces download the program gSurface . It displays g, E0 and E .The surfaces can be rotated and viewed from different directions.

Projects  | ABC Tutorials  | IT Tutorials  |   Home


Warning: include(../../../footer.php) [function.include]: failed to open stream: No such file or directory in /usr111/home/s/i/siberia/public_html/u_az/public_html/projects/gxyz/gxyz1.php on line 151

Warning: include() [function.include]: Failed opening '../../../footer.php' for inclusion (include_path='.:/usr/locl/lib/php') in /usr111/home/s/i/siberia/public_html/u_az/public_html/projects/gxyz/gxyz1.php on line 151